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International Baccalaureate IB Chemistry
2.1.1 Formation of cations and anions
Predict the charge of an ion from the electron configuration of the atom.
2.1.2 Ionic bond formation
Deduce the formula and name of an ionic compound from its component ions, including polyatomic ions.
2.1.3 Lattice structure of ionic compounds
Explain the physical properties of ionic compounds to include volatility, electrical conductivity and solubility. Include lattice enthalpy as a measure of the strength of the ionic bond in different compounds, influenced by ion radius and charge.
2.2.1 Covalent bond and octet rule
Deduce the Lewis formula of molecules and ions for up to four electron pairs on each atom. Lewis formulas show all the valence electrons (bonding and non‑bonding pairs) in a covalently bonded species. Molecules containing atoms with fewer than an octet of electrons should be covered. Organic and inorganic examples should be used.
2.2.2 Single, double and triple bonds
Explain the relationship between the number of bonds, bond length and bond strength.
2.2.4 VSEPR model
Predict the electron domain geometry and the molecular geometry for species with up to four electron domains.
2.2.5 Bond polarity
Deduce the polar nature of a covalent bond from electronegativity values.
2.2.6 Molecular polarity
Deduce the net dipole moment of a molecule or ion by considering bond polarity and molecular geometry.
2.2.7 Covalent network structures of C and Si
Describe the structures and explain the properties of silicon, silicon dioxide and carbon’s allotropes: diamond, graphite, fullerenes and graphene.
2.2.8 Intermolecular forces
Deduce the types of intermolecular force present from the structural features of covalent molecules. The term “van der Waals forces” should be used as an inclusive term to include dipole–dipole, dipole‑induced dipole, and London (dispersion) forces. Hydrogen bonds occur when hydrogen, being covalently bonded to an electronegative atom, has an attractive interaction on a neighbouring electronegative atom.
2.2.9 Relative strength of intermolecular forces
Explain the physical properties of covalent substances to include volatility, electrical conductivity and solubility in terms of their structure.
2.2.10 Chromatography and retardation factor
Explain, calculate and interpret the retardation factor values, R_F.
2.2.11 Resonance structures
Deduce resonance structures of molecules and ions.
2.2.12 Benzene resonance
Discuss the structure of benzene from physical and chemical evidence.
2.2.13 Expanded octet molecules
Visually represent Lewis formulas for species with five and six electron domains around the central atom. Deduce the electron domain geometry and the molecular geometry for these species using the VSEPR model.
2.2.14 Formal charge and preferred Lewis structures
Apply formal charge to determine a preferred Lewis formula from different Lewis formulas for a species.
2.2.15 Sigma and pi bonds
Deduce the presence of sigma bonds and pi bonds in molecules and ions.
2.2.16 Hybridization & Geometry
Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals for bonding. Analyse the hybridization and bond formation in molecules and ions. Identify the relationships between Lewis formulas, electron domains, molecular geometry and type of hybridization. Predict the geometry around an atom from its hybridization, and vice versa. Include both organic and inorganic examples. Only $sp$, $sp^2$ and $sp^3$ hybridization need to be covered.
2.3.1 Metallic bond definition
Explain the electrical conductivity, thermal conductivity and malleability of metals.
2.3.2 Strength of metallic bond and melting points
Explain trends in melting points of s and p block metals.
2.3.3 Transition Metals: Properties
Transition elements and delocalised d‑electrons Explain the high melting point and electrical conductivity of transition elements.
2.4.1 Bonding continuum and bonding triangle
Use bonding models to explain the properties of a material.
2.4.2 Position in the bonding triangle
Determine the position of a compound in the bonding triangle from electronegativity data. Predict the properties of a compound based on its position in the bonding triangle.
2.4.3 Alloys and non‑directional bonding
Explain the properties of alloys in terms of non‑directional bonding.
2.4.4 Polymers and monomers
Describe the common properties of plastics in terms of their structure.
2.4.5 Addition polymers
Represent the repeating unit of an addition polymer from given monomer structures.
2.4.6 Condensation polymers
Represent the repeating unit of polyamides and polyesters from given monomer structures.